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Looking for filler episodes? View the filler guide.
| # | Title | Aired | Type |
|---|---|---|---|
| 1 | The Day a New Demon was Born | Oct 6, 2006 | Canon |
| 2 | The White Knight Awakens | Oct 13, 2006 | Canon |
| 3 | The False Classmate | Oct 20, 2006 | Canon |
| 4 | His Name is Zero | Oct 27, 2006 | Canon |
| 5 | The Princess and the Witch | Nov 3, 2006 | Canon |
| 6 | The Stolen Mask | Nov 10, 2006 | Canon |
| 7 | Attack Cornelia | Nov 17, 2006 | Canon |
| 8 | The Black Knights | Nov 24, 2006 | Canon |
| 9 | Refrain | Dec 8, 2006 | Canon |
| 10 | Guren Dances | Dec 15, 2006 | Canon |
| 11 | Battle for Narita | Dec 22, 2006 | Canon |
| 12 | The Messenger from Kyoto | Jan 5, 2007 | Canon |
| 13 | Shirley at Gunpoint | Jan 12, 2007 | Canon |
| 14 | Geass vs. Geass | Jan 19, 2007 | Canon |
| 15 | Cheering Mao | Jan 26, 2007 | Canon |
| 16 | Nunnally Held Hostage | Feb 2, 2007 | Canon |
| 17 | Knight | Feb 9, 2007 | Canon |
| 18 | I Order you, Suzaku Kururugi | Feb 23, 2007 | Canon |
| 19 | Island of the Gods | Mar 2, 2007 | Canon |
| 20 | Battle at Kyushu | Mar 9, 2007 | Canon |
| 21 | The School Festival Declaration | Mar 16, 2007 | Canon |
| 22 | Bloodstained Euphy | Mar 23, 2007 | Canon |
| 23 | At Least with Sorrow | Mar 30, 2007 | Canon |
| 24 | The Collapsing Stage | Jul 29, 2007 | Canon |
| 25 | Zero | Jul 29, 2007 | Canon |